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铅酸蓄电池镀铅泡沫碳化硅正极

邹智敏 , 刘旭东 , 曹小明 , 张劲松

材料研究学报

研究了镀铅泡沫碳化硅集流体的结构对铅酸蓄电池极板的设计参数、正极活性物质利用率的影响. 镀铅泡沫碳化硅集流体明显降低了集流体的表观密度和阳极板的$\gamma$参数, 显著提高了活性物质的利用率, 延长了电池的循环寿命. 集流体的“三明治”结构改善了极板内的电流分布, 降低了电压降, 明显提高了铅酸蓄电池活性物质的利用率和大电流放电的能力.

关键词: 复合材料 , reticulated SiC , collector of sandwich structure

PREPARATION OF LEAD-ACID BATTERY USING ELECTROPLATED RETICULATED SiC AS THE POSITIVE CURRENT COLLECTOR

Z.M.Zou , X.M.Cao , C.Tian , J.S.Zhang

金属学报(英文版)

The possibility of using Pb-electroplated reticulated SiC as the positive current collector for lead-acid batteries was investigated. Reticulated SiC with two aperture sizes (3 and 2ram) were tested as the substrate of positive electrode. It was found that the reticulated SiC has an excellent corrosion resistance in H2SO4 solution, and the Pb layer electroplated on reticulated SiC showed analogous electrochemical behavior to metal Pb. Preliminary test of the battery performance indicated that the utilization efficiency of the positive active mass of new designed batteries are improved compared with the conventional batteries. The improvement could be ascribed to the high specific surface area of the reticulated structured positive current collector, which was further supported by the even better performance of the battery made from a smaller aperture size (2ram) reticulated SiC as the substrate of the positive electrode.

关键词: lead-acid battery , null , null

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